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Title: Kinetic study of NaBH4 hydrolysis over carbon supported ruthenium
Authors: Shang, Yinghong
Chen, Rui
Jiang, G.
Keywords: Sodium borohydride
Kinetics
Hydrolysis
Ruthenium
Issue Date: 2008
Publisher: © Elsevier
Citation: SHANG, Y., CHEN, R. and JIANG, G., 2008. Kinetic study of NaBH4 hydrolysis over carbon supported ruthenium. International Journal of Hydrogen Energy, 33(22), pp. 6719-6726
Abstract: The effects of temperature and the concentrations of NaBH4, NaBO2 and NaOH on the rate of NaBH4 hydrolysis over carbon supported ruthenium catalyst were investigated using isothermal rate data extracted from non-isothermal reactions. It was shown that the hydrolysis was a zero-order reaction with respect to the concentration of NaBH4 and the reaction rate decreased with the increase of OH- concentration. A rate expression was then derived to correlate the hydrolysis rate with the temperature and NaOH concentration.
Version: Accepted for publication
DOI: 10.1016/j.ijhydene.2008.07.069
URI: https://dspace.lboro.ac.uk/2134/8302
Publisher Link: http://dx.doi.org/10.1016/j.ijhydene.2008.07.069
ISSN: 0360-3199
Appears in Collections:Published Articles (Aeronautical and Automotive Engineering)

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